I've met exactly one man in my life who I felt like this about. I would probably die of shock that there were two men who met my emotional and spiritual desires.
I digress.
The question you pose is a silly one. Of course all things being equal I would choose the man I'm more attracted to.
But the fact is that all things are not equal. And attraction grows.
A recent example: I started going to a meetup group where there was a man who I initially thought, "Wow, this man is uncommonly unattractive." He's married, so I assumed he had some other redeeming qualities.
Then one day we were chatting during the meetup and he sparked my interest talking about philosophy. That one two-hour long conversation completely changed the way I viewed his physical attributes.
There are some women who will never be attracted to a man simply because he is an amazing person. I'm not one of them.
I also think the men who ask questions like this are talking about a "10". They're saying, "I'm a 2 and no 10 is ever going to be attracted to me." And for the most part that is true. But why as a 2 can you not pursue a 3? or a 4? There are plenty of less attractive women that would love to have a partner.
It's all you red pillers out there who believe you are owed the most attractive woman in the room when you yourself are not the most attractive man in the room. I promise you, throughout the ages, plenty of ugly men have fallen in love and gotten married. But if you're ugly on the inside as well, then there's definitely no chance. And playing the victim is ALWAYS an ugly look.